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The Resource Diffusion of reactive molecules in solids and melts, Robert H. Doremus

Diffusion of reactive molecules in solids and melts, Robert H. Doremus

Label
Diffusion of reactive molecules in solids and melts
Title
Diffusion of reactive molecules in solids and melts
Statement of responsibility
Robert H. Doremus
Creator
Subject
Language
eng
Summary
"Diffusion of Reactive Molecules in Solids and Melts presents an up-to-date and comprehensive survey of the subject written for geologists, professionals working in fiber optics, graduate students, and researchers in materials science and solid-state physics."--Jacket
Cataloging source
DLC
http://library.link/vocab/creatorName
Doremus, R. H
Dewey number
541/.0421
Illustrations
illustrations
Index
index present
LC call number
QD478
LC item number
.D67 2002
Literary form
non fiction
Nature of contents
bibliography
http://library.link/vocab/subjectName
  • Diffusion
  • Solid state chemistry
Label
Diffusion of reactive molecules in solids and melts, Robert H. Doremus
Instantiates
Publication
Note
"A Wiley-Interscience publication."
Bibliography note
Includes bibliographical references and indexes
Carrier category
volume
Carrier category code
  • nc
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
  • 3
  • 80
  • 6.5
  • Experiments of Spitzer and Ligenza at 650[degree]C, and Rigo et al. from 400 to 900[degree]C
  • 86
  • 6.6
  • Experiments of Wakabayashi and Tomozawa at 350 and 450[degree]C
  • 90
  • 6.7
  • Experiments of Rauch et al. and Lanford et al. at Temperatures of 200 to 90[degree]C
  • 91
  • 1.4
  • 7
  • Diffusion, Reaction, and Exchange of Water in Quartz
  • 96
  • 7.2
  • Structure of Quartz
  • 97
  • 7.3
  • Experiments of Kats on Hydrogen-Deuterium Exchange
  • 98
  • 7.4
  • Outline of the Book
  • Experiments on [superscript 18]O-[superscript 16]O Exchange
  • 101
  • 7.5
  • Experiments of Dersch and Rauch at Temperatures of 200[degree]C and Lower
  • 104
  • 8
  • Diffusion and Reaction of Water in Rhyolite Glass (Obsidian)
  • 108
  • 8.2
  • Diffusion-Reaction Model
  • 4
  • 109
  • 8.3
  • Analysis of High-Temperature Diffusion Profiles
  • 111
  • 8.4
  • Analysis of Low-Temperature Profiles
  • 114
  • 9
  • Diffusion and Reaction of Water in Oxides
  • 120
  • 1.5
  • 9.2
  • Equations
  • 121
  • 9.3
  • Diffusion of Water in Pyrope and Calcite
  • 122
  • 9.4
  • Comparison of Experimental Activation Energies for Diffusion of Water in Oxides with Ionic Porosity
  • 124
  • 10
  • Omissions
  • Speciation of Water in Silicate Glasses and Melts
  • 129
  • 10.2
  • Langmuir Model for Speciation
  • 130
  • 10.3
  • Comparison with Experiment
  • 132
  • 10.4
  • Solubility of Water
  • 7
  • 136
  • 10.5
  • Partial Molar Volume
  • 140
  • 11
  • Hydrogen in Oxides
  • 148
  • 11.2
  • Hydrogen in Silica Glass
  • 149
  • 2
  • 11.3
  • Hydrogen in Fiber Optic Cables of Silica
  • 154
  • 11.4
  • Hydrogen in Multicomponent Silicate Glasses
  • 158
  • 11.5
  • Hydrogen in Crystalline Oxides
  • 159
  • 12
  • Diffusion Without Chemical Reaction
  • Diffusion of Oxygen in Nominally Dry Oxides
  • 163
  • 12.2
  • Diffusion of Oxygen in Silica Glass
  • 164
  • 12.3
  • Molecular Transport of Oxygen
  • 170
  • 12.4
  • Oxygen Transport by Ions
  • 9
  • 172
  • 12.5
  • Experimental Activation Energies
  • 175
  • 12.6
  • Further Considerations of Mechanisms
  • 177
  • 12.7
  • Diffusion of Oxygen in Nominally Dry Silicate Melts
  • 180
  • 1.1
  • 2.2
  • 13
  • Oxidation State
  • 185
  • 13.2
  • Dissolved Gases
  • 186
  • 13.3
  • Metals and Oxygen
  • 193
  • 13.4
  • Fundamental Diffusion Equations
  • Ions with Multiple Valence States and the Phase Rule
  • 193
  • 13.5
  • Oxidation with Transport of Cations
  • 197
  • 14
  • Diffusion in Silicon: Fast and Intermediate Diffusers
  • 199
  • 14.2
  • Classification of Diffusing Atoms
  • 9
  • 200
  • 14.3
  • Interstitials, Vacancies, and Fast Diffusers in Silicon
  • 202
  • 14.4
  • Exchange or Kick-Out Mechanism and Diffusion of Intermediate Diffusers in Single-Crystal, r Dislocation-Free Silicon
  • 205
  • 14.5
  • Influence of Dislocations in Silicon on Intermediate Diffusers
  • 214
  • 2.3
  • 14.6
  • Diffusion in Amorphous Silicon
  • 215
  • 14.7
  • Summary and Subsequent Chapters
  • 216
  • 15
  • Diffusion of Hydrogen in Silicon
  • 219
  • 15.2
  • Infinite and Semi-Infinite Geometries
  • Mechanisms of Hydrogen Diffusion in Silicon
  • 220
  • 15.3
  • Equations
  • 223
  • 15.4
  • Comparison with Experiments
  • 229
  • 16
  • Diffusion of Oxygen and Silicon in Silicon: Silicon Monoxide Model
  • 12
  • 241
  • 16.2
  • Structure of Dissolved SiO
  • 244
  • 16.3
  • Infrared Spectra and Dichroism
  • 245
  • 16.4
  • Diffusion of Oxygen, Infrared Dichroism, and Internal Friction
  • 246
  • 2.4
  • 16.5
  • Fast Diffusion of Oxygen
  • 247
  • 16.6
  • Diffusion of Silicon
  • 248
  • 17
  • Diffusion of Group III, IV, and V Elements in Silicon
  • 253
  • 17.2
  • Plane Sheet
  • Diffusion Coefficients and Activation Energies for Group III, IV, and V Elements
  • 254
  • 17.3
  • Mechanisms of Diffusion and Reaction
  • 258
  • 17.4
  • Concentration Dependence of Effective Diffusion Coefficients of Group III and V Elements in Silicon
  • 262
  • 17.5
  • Internal Friction of Silicon
  • 14
  • 267
  • 17.6
  • Influence of Other Factors on Dopant Diffusion in Silicon
  • 268
  • 18
  • Diffusion in Germanium
  • 273
  • 18.2
  • Measurements of Diffusion Coefficients in Germanium and Silicon
  • 274
  • 2.5
  • 18.3
  • Diffusion Profiles in Germanium
  • 275
  • 18.4
  • Mechanisms of Diffusion in Germanium
  • 279
  • Importance
  • Permeation Through a Membrane
  • 16
  • 2.6
  • Diffusion Coefficient a Function of Concentration
  • 19
  • 3
  • Diffusion and Reaction with Local Equilibrium
  • 23
  • 3.2
  • Reaction Experiments
  • 1
  • 24
  • 3.3
  • Exchange Experiments
  • 27
  • 3.4
  • Pressure Effects
  • 29
  • 3.5
  • Moving Boundary-Tarnishing Reactions
  • 30
  • 1.2
  • 4
  • Diffusion and Nonequilibrium Reactions
  • 36
  • 4.2
  • No Local Equilibrium, Forward Reaction Only
  • 37
  • 4.3
  • No Local Equilibrium, First-Order Forward and Reverse Reactions
  • 42
  • 4.4
  • Defects
  • No Equilibrium, First-Order Forward Reaction, Second-Order Reverse Reaction
  • 49
  • 4.5
  • No Local Equilibrium, Tracer Diffusion
  • 52
  • 4.6
  • Time Ranges of Validity of Equations
  • 54
  • 4.7
  • Surface Exchange
  • 2
  • 55
  • Appendix
  • Error Functions of Complex Argument
  • 57
  • 5
  • Structure and Sizes of Atoms and Molecules
  • 59
  • 5.2
  • Electron Distributions Around Atoms and Molecules
  • 60
  • 1.3
  • 5.3
  • Sizes of Gaseous Atoms and Molecules Dissolved in Solids and Melts
  • 62
  • 5.4
  • Sizes of Ions in Solids and Melts, and Openness of Solid Structures
  • 68
  • 5.5
  • Monoxides
  • 70
  • 6
  • Diffusion-Reaction Mechanisms
  • Diffusion and Reaction of Water in Silica Glass
  • 74
  • 6.2
  • Structure of Silica Glass
  • 76
  • 6.3
  • Gas Solubility in Silica Glass
  • 78
  • 6.4
  • Experiments of Roberts and Co-Workers at Temperatures of 700 to 1200[degree]C
Control code
47643354
Dimensions
25 cm
Extent
xii, 293 pages
Isbn
9780471385455
Isbn Type
(acid-free paper)
Lccn
2001049246
Media category
unmediated
Media MARC source
rdamedia
Media type code
  • n
Other physical details
illustrations
Label
Diffusion of reactive molecules in solids and melts, Robert H. Doremus
Publication
Note
"A Wiley-Interscience publication."
Bibliography note
Includes bibliographical references and indexes
Carrier category
volume
Carrier category code
  • nc
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
  • 3
  • 80
  • 6.5
  • Experiments of Spitzer and Ligenza at 650[degree]C, and Rigo et al. from 400 to 900[degree]C
  • 86
  • 6.6
  • Experiments of Wakabayashi and Tomozawa at 350 and 450[degree]C
  • 90
  • 6.7
  • Experiments of Rauch et al. and Lanford et al. at Temperatures of 200 to 90[degree]C
  • 91
  • 1.4
  • 7
  • Diffusion, Reaction, and Exchange of Water in Quartz
  • 96
  • 7.2
  • Structure of Quartz
  • 97
  • 7.3
  • Experiments of Kats on Hydrogen-Deuterium Exchange
  • 98
  • 7.4
  • Outline of the Book
  • Experiments on [superscript 18]O-[superscript 16]O Exchange
  • 101
  • 7.5
  • Experiments of Dersch and Rauch at Temperatures of 200[degree]C and Lower
  • 104
  • 8
  • Diffusion and Reaction of Water in Rhyolite Glass (Obsidian)
  • 108
  • 8.2
  • Diffusion-Reaction Model
  • 4
  • 109
  • 8.3
  • Analysis of High-Temperature Diffusion Profiles
  • 111
  • 8.4
  • Analysis of Low-Temperature Profiles
  • 114
  • 9
  • Diffusion and Reaction of Water in Oxides
  • 120
  • 1.5
  • 9.2
  • Equations
  • 121
  • 9.3
  • Diffusion of Water in Pyrope and Calcite
  • 122
  • 9.4
  • Comparison of Experimental Activation Energies for Diffusion of Water in Oxides with Ionic Porosity
  • 124
  • 10
  • Omissions
  • Speciation of Water in Silicate Glasses and Melts
  • 129
  • 10.2
  • Langmuir Model for Speciation
  • 130
  • 10.3
  • Comparison with Experiment
  • 132
  • 10.4
  • Solubility of Water
  • 7
  • 136
  • 10.5
  • Partial Molar Volume
  • 140
  • 11
  • Hydrogen in Oxides
  • 148
  • 11.2
  • Hydrogen in Silica Glass
  • 149
  • 2
  • 11.3
  • Hydrogen in Fiber Optic Cables of Silica
  • 154
  • 11.4
  • Hydrogen in Multicomponent Silicate Glasses
  • 158
  • 11.5
  • Hydrogen in Crystalline Oxides
  • 159
  • 12
  • Diffusion Without Chemical Reaction
  • Diffusion of Oxygen in Nominally Dry Oxides
  • 163
  • 12.2
  • Diffusion of Oxygen in Silica Glass
  • 164
  • 12.3
  • Molecular Transport of Oxygen
  • 170
  • 12.4
  • Oxygen Transport by Ions
  • 9
  • 172
  • 12.5
  • Experimental Activation Energies
  • 175
  • 12.6
  • Further Considerations of Mechanisms
  • 177
  • 12.7
  • Diffusion of Oxygen in Nominally Dry Silicate Melts
  • 180
  • 1.1
  • 2.2
  • 13
  • Oxidation State
  • 185
  • 13.2
  • Dissolved Gases
  • 186
  • 13.3
  • Metals and Oxygen
  • 193
  • 13.4
  • Fundamental Diffusion Equations
  • Ions with Multiple Valence States and the Phase Rule
  • 193
  • 13.5
  • Oxidation with Transport of Cations
  • 197
  • 14
  • Diffusion in Silicon: Fast and Intermediate Diffusers
  • 199
  • 14.2
  • Classification of Diffusing Atoms
  • 9
  • 200
  • 14.3
  • Interstitials, Vacancies, and Fast Diffusers in Silicon
  • 202
  • 14.4
  • Exchange or Kick-Out Mechanism and Diffusion of Intermediate Diffusers in Single-Crystal, r Dislocation-Free Silicon
  • 205
  • 14.5
  • Influence of Dislocations in Silicon on Intermediate Diffusers
  • 214
  • 2.3
  • 14.6
  • Diffusion in Amorphous Silicon
  • 215
  • 14.7
  • Summary and Subsequent Chapters
  • 216
  • 15
  • Diffusion of Hydrogen in Silicon
  • 219
  • 15.2
  • Infinite and Semi-Infinite Geometries
  • Mechanisms of Hydrogen Diffusion in Silicon
  • 220
  • 15.3
  • Equations
  • 223
  • 15.4
  • Comparison with Experiments
  • 229
  • 16
  • Diffusion of Oxygen and Silicon in Silicon: Silicon Monoxide Model
  • 12
  • 241
  • 16.2
  • Structure of Dissolved SiO
  • 244
  • 16.3
  • Infrared Spectra and Dichroism
  • 245
  • 16.4
  • Diffusion of Oxygen, Infrared Dichroism, and Internal Friction
  • 246
  • 2.4
  • 16.5
  • Fast Diffusion of Oxygen
  • 247
  • 16.6
  • Diffusion of Silicon
  • 248
  • 17
  • Diffusion of Group III, IV, and V Elements in Silicon
  • 253
  • 17.2
  • Plane Sheet
  • Diffusion Coefficients and Activation Energies for Group III, IV, and V Elements
  • 254
  • 17.3
  • Mechanisms of Diffusion and Reaction
  • 258
  • 17.4
  • Concentration Dependence of Effective Diffusion Coefficients of Group III and V Elements in Silicon
  • 262
  • 17.5
  • Internal Friction of Silicon
  • 14
  • 267
  • 17.6
  • Influence of Other Factors on Dopant Diffusion in Silicon
  • 268
  • 18
  • Diffusion in Germanium
  • 273
  • 18.2
  • Measurements of Diffusion Coefficients in Germanium and Silicon
  • 274
  • 2.5
  • 18.3
  • Diffusion Profiles in Germanium
  • 275
  • 18.4
  • Mechanisms of Diffusion in Germanium
  • 279
  • Importance
  • Permeation Through a Membrane
  • 16
  • 2.6
  • Diffusion Coefficient a Function of Concentration
  • 19
  • 3
  • Diffusion and Reaction with Local Equilibrium
  • 23
  • 3.2
  • Reaction Experiments
  • 1
  • 24
  • 3.3
  • Exchange Experiments
  • 27
  • 3.4
  • Pressure Effects
  • 29
  • 3.5
  • Moving Boundary-Tarnishing Reactions
  • 30
  • 1.2
  • 4
  • Diffusion and Nonequilibrium Reactions
  • 36
  • 4.2
  • No Local Equilibrium, Forward Reaction Only
  • 37
  • 4.3
  • No Local Equilibrium, First-Order Forward and Reverse Reactions
  • 42
  • 4.4
  • Defects
  • No Equilibrium, First-Order Forward Reaction, Second-Order Reverse Reaction
  • 49
  • 4.5
  • No Local Equilibrium, Tracer Diffusion
  • 52
  • 4.6
  • Time Ranges of Validity of Equations
  • 54
  • 4.7
  • Surface Exchange
  • 2
  • 55
  • Appendix
  • Error Functions of Complex Argument
  • 57
  • 5
  • Structure and Sizes of Atoms and Molecules
  • 59
  • 5.2
  • Electron Distributions Around Atoms and Molecules
  • 60
  • 1.3
  • 5.3
  • Sizes of Gaseous Atoms and Molecules Dissolved in Solids and Melts
  • 62
  • 5.4
  • Sizes of Ions in Solids and Melts, and Openness of Solid Structures
  • 68
  • 5.5
  • Monoxides
  • 70
  • 6
  • Diffusion-Reaction Mechanisms
  • Diffusion and Reaction of Water in Silica Glass
  • 74
  • 6.2
  • Structure of Silica Glass
  • 76
  • 6.3
  • Gas Solubility in Silica Glass
  • 78
  • 6.4
  • Experiments of Roberts and Co-Workers at Temperatures of 700 to 1200[degree]C
Control code
47643354
Dimensions
25 cm
Extent
xii, 293 pages
Isbn
9780471385455
Isbn Type
(acid-free paper)
Lccn
2001049246
Media category
unmediated
Media MARC source
rdamedia
Media type code
  • n
Other physical details
illustrations

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