The Resource Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds, Gerardo B. Márquez, (electronic resource)

Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds, Gerardo B. Márquez, (electronic resource)

Label
Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds
Title
Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds
Statement of responsibility
Gerardo B. Márquez
Creator
Contributor
Thesis advisor
Subject
Genre
Language
eng
Summary
This dissertation encompasses the investigation of two distinct subjects. In the first part, which is in the area of molecular self-assembly, the complexation of organonitrile aryl compounds with three different types of silver (I) salts is examined in the solid state. The assembly of 1-(2,2-dicyanovinyl)naphthalene with silver hexafluoroantimonate resulted in a cationic 3D network. Complexation of 4-(2,2-dicyanovinyl)biphenyl with silver tetrafluoroborate and hexafluoroantimonate from benzene generated two similar structures. While the former displays a cationic 3D network, the latter is defined by cationic 2D sheets. Complexation of 9-(2,2-dicyanovinyl)anthracene with silver hexafluoroantimonate from toluene afforded a cationic 2D ribbon, and from benzene, it yielded cationic 2D sheets. These complexes contained solvent bonded to their structures. However, the hexafluoroantimonate ion is nonbonding. The crystal association of 1,4-bis(cyanovinyl)benzene with silver triflate from benzene yielded neutral 2D sheets whose imperfect-rectangular macrocyclic arrangements are interconnected on both sides by bridges of benzene. On the other hand, the assembly of 1,3- bis(cyanovinyl)benzene with silver triflate from benzene afforded a neutral 3D network formed by two interconnected rings. Solvent and triflate counterions are bonded in both complexes. In the second part of this dissertation, the focus was on the synthesis of four linear PAHs containing a perylene center formed by the connection of two substituted fluoranthene units. Our synthetic approach included the elaboration of fluoranthene building blocks (monomers), followed by the coupling of the monomers resulting in dimers, and finally, ring closure of those dimers, which form the target structures. All of the stages were monitored by mass spectrometry, 1H NMR, and 13C NMR spectroscopy. Out of four dimers, only one successfully underwent ring closure. The UV/Vis absorption and fluorescence spectra for the only obtained target compoundevaluated in chloroform showed absorption bands at 318, 352, 518, 558, and 606 nm and emission bands at 615 and 667 nm. The fluorescence quantum yield at 558 nm was zF = 0.21, and at 606 nm was zF = 0.4. Since the differentiation between the targets relies on the substitution pattern, these results suggest that changes in the fluoranthene moiety render changes in the reactivity through the coupling reaction
Cataloging source
UMK
http://library.link/vocab/creatorDate
1965-
http://library.link/vocab/creatorName
Márquez, Gerardo B.
Degree
Ph.D.
Dissertation year
2012.
Granting institution
Dept. of Chemistry and School of Pharmacy. University of Missouri-Kansas City
Illustrations
illustrations
Index
no index present
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
  • theses
http://library.link/vocab/relatedWorkOrContributorDate
1963-
http://library.link/vocab/relatedWorkOrContributorName
Kilway, Kathleen V.
http://library.link/vocab/subjectName
  • Polycyclic aromatic hydrocarbons
  • Silver salts
Label
Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds, Gerardo B. Márquez, (electronic resource)
Instantiates
Publication
Note
  • "A dissertation in Chemistry and Pharmaceutical Sciences."
  • Advisor: Kathleen V. Kilway
  • Vita
Antecedent source
not applicable
Bibliography note
Includes bibliographical references (pages 127-138)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
black and white
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Chapter 1. Introduction and literature review -- Factors that affect self-assembly -- Objectives and synthetic approaches -- Results and discussion -- Summary -- Conclusions -- Experimental section -- Chapter 2. Introduction and literature review -- From planar to highly twisted PAHs -- Methods used for the building of PAHs -- Perylene structures -- Objectives and synthetic approaches -- Results and discussion -- Conclusions -- Experimental section
Control code
823938873
Dimensions
unknown
Extent
1 online resource (155 pages)
File format
one file format
Form of item
online
Level of compression
mixed
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
color illustrations
Quality assurance targets
not applicable
Specific material designation
remote
System control number
(OCoLC)823938873
System details
  • The full text of the dissertation is available as an Adobe Acrobat .pdf file; Adobe Acrobat Reader required to view the file
  • Mode of access: World Wide Web
Label
Molecular assembly of polycyanoarenes with silver salts and synthesis of polycyclic aromatic hydrocarbonds, Gerardo B. Márquez, (electronic resource)
Publication
Note
  • "A dissertation in Chemistry and Pharmaceutical Sciences."
  • Advisor: Kathleen V. Kilway
  • Vita
Antecedent source
not applicable
Bibliography note
Includes bibliographical references (pages 127-138)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
black and white
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Chapter 1. Introduction and literature review -- Factors that affect self-assembly -- Objectives and synthetic approaches -- Results and discussion -- Summary -- Conclusions -- Experimental section -- Chapter 2. Introduction and literature review -- From planar to highly twisted PAHs -- Methods used for the building of PAHs -- Perylene structures -- Objectives and synthetic approaches -- Results and discussion -- Conclusions -- Experimental section
Control code
823938873
Dimensions
unknown
Extent
1 online resource (155 pages)
File format
one file format
Form of item
online
Level of compression
mixed
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
color illustrations
Quality assurance targets
not applicable
Specific material designation
remote
System control number
(OCoLC)823938873
System details
  • The full text of the dissertation is available as an Adobe Acrobat .pdf file; Adobe Acrobat Reader required to view the file
  • Mode of access: World Wide Web

Library Locations

  • Ellis LibraryBorrow it
    1020 Lowry Street, Columbia, MO, 65201, US
    38.944491 -92.326012
  • Engineering Library & Technology CommonsBorrow it
    W2001 Lafferre Hall, Columbia, MO, 65211, US
    38.946102 -92.330125
  • Fisher Delta Research CenterBorrow it
    2-64 Agricultural Bldg, Columbia, MO, 65201, US
    38.958397 -92.303491
  • Geological Sciences LibraryBorrow it
    201 Geological Sciences, Columbia, MO, 65211, US
    38.947375 -92.329062
  • J. Otto Lottes Health Sciences LibraryBorrow it
    1 Hospital Dr, Columbia, MO, 65201, US
    38.939544 -92.328377
  • Journalism LibraryBorrow it
    102 Reynolds Jrnlism Institute, Columbia, MO, 65211, US
    38.947290 -92.328025
  • Mathematical Sciences LibraryBorrow it
    104 Ellis Library, Columbia, MO, 65201, US
    38.944377 -92.326537
  • University ArchivesBorrow it
    Columbia, MO, 65201, US
  • University Archives McAlester AnnexBorrow it
    703 Lewis Hall, Columbia, MO, 65211, US
    38.934630 -92.342290
  • University of Missouri Libraries DepositoryBorrow it
    2908 Lemone Blvd, Columbia, MO, 65211, US
    38.919360 -92.291620
  • Zalk Veterinary Medical LibraryBorrow it
    Veterinary Medicine West, Columbia, MO, 65211, US
    38.941099 -92.317911
Processing Feedback ...