The Resource Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes, by Jian-Jun Li

Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes, by Jian-Jun Li

Label
Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes
Title
Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes
Statement of responsibility
by Jian-Jun Li
Title variation
  • Platinum oxo, imido and hydrazido complexes
  • Platinum II hydroxo, oxo, amido, imido and hydrazido complexes
  • Platinum (II) hydroxo, oxo, amido, imido and hydrazido complexes
Creator
Subject
Language
eng
Summary
Late transition metal oxo and imido complexes are important models for catalytic reactions involving oxygen and nitrogen transfer. The subject of this dissertation is the synthesis and reactivity study of a series of platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes. The platinum(II) hydroxo complex (L$\sb2$Pt($\mu$-OH)) $\rm\sb2X\sb2$ is prepared from the reaction of L$\rm\sb2PtCl\sb2$ with two equivalents of AgX. Deprotonation of the hydroxo complex (L$\rm\sb2Pt(\mu$-OH)) $\sb2\sp{2+}$ yields corresponding oxo complexes. The site of deprotonation depends on the phosphine ligands. Pt(II) $\mu$-amido complexes are synthesized from the reaction of $\mu$-hydroxo complexes (L$\rm\sb2Pt(\mu$-OH)) $\rm\sb2(BF\sb4)\sb2$ with amines H$\sb2$NR. The result of the reaction depends on the ligand L$\sb2$ of the $\mu$-hydroxo complexes as well as on the R group of the amines. Treating (L$\rm\sb2Pt(\mu$-OH)) $\rm\sb2(BF\sb4)\sb2$ with two equivalents of H$\rm\sb2NNH\sb2$ generates an unusual hydrazido complex (L$\rm\sb2Pt(\mu$-NHNH$\rm\sb2)\rbrack\sb2(BF\sb4)\sb2$ which can be deprotonated to give ((dppm-H)Pt($\mu$-NHNH$\sb2)\rbrack\sb2$
Additional physical form
Also available on the Internet.
Cataloging source
MUU
http://library.link/vocab/creatorDate
1967-
http://library.link/vocab/creatorName
Li, Jian-Jun
Degree
Ph. D.
Dissertation year
1996.
Government publication
government publication of a state province territory dependency etc
Granting institution
University of Missouri-Columbia
Illustrations
illustrations
Index
no index present
Literary form
non fiction
Nature of contents
bibliography
http://library.link/vocab/subjectName
  • Platinum
  • Organometallic chemistry
  • Inorganic compounds
  • Inorganic compounds
  • Organometallic compounds
Target audience
specialized
Label
Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes, by Jian-Jun Li
Instantiates
Publication
Note
  • Typescript
  • Vita
Bibliography note
Includes bibliographical references (leaves 167-175)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Control code
36443247
Dimensions
29 cm
Dimensions
unknown
Extent
xiii, 176 leaves
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
illustrations
Specific material designation
remote
Label
Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes, by Jian-Jun Li
Publication
Note
  • Typescript
  • Vita
Bibliography note
Includes bibliographical references (leaves 167-175)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Control code
36443247
Dimensions
29 cm
Dimensions
unknown
Extent
xiii, 176 leaves
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
illustrations
Specific material designation
remote

Library Locations

    • Ellis LibraryBorrow it
      1020 Lowry Street, Columbia, MO, 65201, US
      38.944491 -92.326012
    • University of Missouri Libraries DepositoryBorrow it
      2908 Lemone Blvd, Columbia, MO, 65211, US
      38.919360 -92.291620
Processing Feedback ...