The Resource The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons, by James Brown

The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons, by James Brown

Label
The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons
Title
The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons
Statement of responsibility
by James Brown
Creator
Subject
Language
eng
Summary
Transition metals provide an unique opportunity to investigate the chemistry of Polycyclic aromatic carbon compounds (PACs). This paper focuses on the initial work necessary to establish an understanding of the chemistry of this class of compounds. Initial investigations have demonstrated the potential for expansion and functionalization of PACs by nickel. Zero valent nickel readily inserts into the carbon-halogen bond of PACs to yield an oxidative addition product. In particular, 1,8-dibromonaphthalene reacts with a mixture of Ni(COD) 2 and trimethylphosphine to form the oxidative addition product Ni(PMe 2 ) 2 (Br)(C 10 H 6 Br). It is further possible to carry out a reduction of this product with Na/Hg to form perylene or, in the presence of an alkyne, form the 1,2-disubstituted acenaphthylene. The results show promise for the further development of larger PACs using the techniques that have been explored, and the potential for their development will be discussed. (Abstract shortened by UMI.)
Additional physical form
Also available on the Internet.
Cataloging source
MUU
http://library.link/vocab/creatorDate
1978-
http://library.link/vocab/creatorName
Brown, James S.
Degree
M.S.
Dissertation year
2004.
Government publication
government publication of a state province territory dependency etc
Granting institution
University of Missouri-Columbia
Illustrations
illustrations
Index
no index present
Literary form
non fiction
Nature of contents
  • bibliography
  • theses
http://library.link/vocab/subjectName
  • Polycyclic aromatic compounds
  • Polycyclic aromatic hydrocarbons
  • Nickel
Target audience
specialized
Label
The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons, by James Brown
Instantiates
Publication
Note
Typescript
Bibliography note
Includes bibliographical references (leaves 58-63)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Control code
59668109
Dimensions
29 cm
Extent
viii, 63 leaves
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
illustrations
Specific material designation
remote
Label
The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons, by James Brown
Publication
Note
Typescript
Bibliography note
Includes bibliographical references (leaves 58-63)
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Control code
59668109
Dimensions
29 cm
Extent
viii, 63 leaves
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
illustrations
Specific material designation
remote

Library Locations

    • University of Missouri Libraries DepositoryBorrow it
      2908 Lemone Blvd, Columbia, MO, 65211, US
      38.919360 -92.291620
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